Single crystal Germanium(Ge)

Germanium single crystals have high hardness, good mechanical properties and thermal conductivity, and are widely used in infrared imaging systems and infrared spectrometer systems. Our company can provide many specifications of monocrystalline germanium blanks and finished products.

Our company can supply many specifications of single crystal germanium blanks and finished products.The shape of the blank contains round, rectangular, drilled, windows, lenses, galvanometers, special shaped etc.

Germanium is a commonly used infrared optical material with high hardness and insolubility in water. Germanium single crystal is an ideal material for CO2 laser lens, window and output coupling mirror because of its good mechanical and thermal conductivity and small absorption at 10.6μm.

Coating refers to coating a transparent electrolyte film or metal film on the surface of the substrate material by physical or chemical methods. The purpose is to change the reflection and transmission characteristics of the material surface to reduce or increase the reflection, beam splitting, color separation, light filtering, polarization and other requirements.We can provide various optical coatings such as anti-reflective films, high-reflective films, spectral films, and metallic films. Broadband anti-reflective films are available for UV, visible, NIR and mid-infrared wavelengths.

Material Standards

●Material: germanium single crystal material with chemical composition of Ge

●Purity: The germanium polycrystalline ingots used for crystal growth shall meet the requirements of GB/T11071. Its purity shall be not less than 99.9999%  (6N) and resistivity not less than 50Ω.cm.

●Growth method:CZ.

●Crystallization quality: No grain boundaries, twins or holes should be observed on the outer walls and end faces of the crystal.

●Appearance quality: The surface of the crystal sidewall is the native surface, and the two end surfaces are the cut surface or the native surface. No contamination, chipping, cracks or scratches on the side walls and both end surfaces.

●Orientation: There are two orientations of germanium single crystals: <100>and <111>.

●Conductivity types: There are two types of germanium single crystals: N-type and P-type.

●Dopant: The dopant for germanium single crystal is shown below.

●Resistivity: The resistivity of a single crystal of germanium is characterized by the resistivity of the head and tail end surfaces of the single crystal. It is divided into the following classes.

●Optical absorption coefficient: The absorption coefficient of germanium crystal should be no more than 0.01cm-1 at 3.0μm and no more than 0.03cm-1 at 10.6μm.

●Refractive index: The refractive index should be in accordance with the following table.

●N-BK7

    N-BK7 is the most commonly used optical glass for processing high quality optical components,, with excellent transmittance from visible to near-infrared wavelengths(350-2000nm), and has a wide range of applications in telescopes, lasers and other fields. N-BK7 is generally chosen when the additional benefits of UV fused silica (very good transmittance and low coefficient of thermal expansion in the UV band) are not required.

●UV fused silica

     UV fused silica has a high transmission from the UV to NIR  (185-2100nm).  In addition, UV fused silica has better uniformity and lower coefficient of thermal expansion than H-K9L (N-BK7), making it particularly suitable for high power laser and imaging applications.

●Calcium fluoride

    Due to its high transmittance and low refractive index within a wavelength of 180nm-8um, calcium fluoride is often used as windows and lenses in spectrometers and thermal imaging systems. In addition, it has good applications in excimer lasers because of its high laser damage threshold.

●Barium fluoride

    Barium fluoride have high transmittance from the 200nm-11um and they are resistant to stronger high-energy radiation. At the same time, barium fluoride has excellent scintillation properties and can be made into various infrared and ultraviolet optical components. However, the disadvantage of barium fluoride is that it is less resistant to water. When exposed to water, the performance degrades significantly at 500℃, but it can be used for applications up to 800℃ in a dry environment. At the same time, barium fluoride has excellent scintillation properties and can be made into various infrared and ultraviolet optical components.It should be noted that when handling barium fluoride material, gloves must be worn at all times and hands must be washed thoroughly after handling.

●Magnesium fluoride 

    Magnesium fluoride is ideal for applications in the wavelength range of 200nm-6um. Compared to other materials, magnesium fluoride is particularly durable in the deep UV and far IR wavelength ranges. Magnesium fluoride is a powerful material for resistance to chemical corrosion, laser damage, mechanical shock and thermal shock. It is harder than calcium fluoride crystals, but relatively soft compared to fused silica, and has a slight hydrolysis. It has a Nucleus hardness of 415 and a refractive index of 1.38.

●Zinc selenide 

    Zinc selenide has high transmittance in the 600nm-16um and is commonly used in thermal imaging, infrared imaging, and medical systems. Also, due to its low absorption, zinc selenide is particularly suitable for use in high-power CO2 lasers. It should be noted that zinc selenide is a relatively soft material (Nucleus hardness 120) and is easily scratched, so it is not recommended for use in harsh environments. Extra care should be taken when holding, and cleaning, pinching or wiping with even force, and it is best to wear gloves or rubber finger covers to prevent tarnishing. Cannot be held with tweezers or other tools.

●Silicon 

    Silicon is suitable for use in the NIR band from 1.2-8um.Because of its low 

    density, silicon is particularly suitable in applications where weight

    requirements are sensitive, especially in the 3-5um . Silicon has a Nucleus 

    hardness of 1150, which is harder than germanium and not as fragile as 

    germanium.It is not suitable for transmission applications in CO2 lasers 

    because of its strong absorption band at 9um.

●Germanium 

    Germanium is suitable for use in the near-infrared band of 2-16um and is well 

    suited for infrared lasers. Due to its high refractive index, minimal surface 

    curvature and low chromatic aberration, germanium does not usually require 

    correction in low power imaging systems. However, germanium is more 

    severely affected by temperature, and the transmittance decreases with

    increasing temperature; therefore, it can only be applied below 100°C. The 

    density of germanium (5.33 g/cm³) is taken into account when designing 

    systems with strict weight requirements. Germanium lenses feature a

    precision diamond lathe turned surface, a feature that makes them well suited

    for a variety of infrared applications, including thermal imaging systems, 

    infrared beam splitters, telemetry, and in the forward-looking infrared (FLIR)

    field.

●CVD ZnS 

    CVD ZnS is the only infrared optical material, other than diamond, that covers visible to long-wave infrared (LWIR), full wavelength and even microwave wavelengths, and is currently the most important LWIR window material. It can be used as windows and lenses for high-resolution thermal imaging systems, as well as for advanced military applications such as "tri-optical" windows and near-infrared laser/dual-color infrared composite windows.